Platinum nanoparticles on electrospun titania nanofibers as hydrogen sensing materials working at room temperature.
نویسندگان
چکیده
Platinum nanoparticles (PtNPs), with diameters of 3-10 nm, were synthesized by water phase reduction, using 3-mercapto-1-propanesulfonate (3MPS) as a hydrophilic capping agent. PtNPs were deposited by a dipcoating technique on titania nanofibers (TiO2NFs), obtained by electrospinning. The investigated properties of the Pt-TiO2 hybrid at room temperature show that this material combines the properties of photoconduction of titania and the photocatalytic activity of the hybrid. To assess the best performance of Pt-TiO2, different measurements were performed at room temperature, comparing hydrogen response under UV of the uncoated TiO2NFs, compared with the Pt-TiO2 system prepared with two different amounts of PtNPs. During the sensing tests toward hydrogen an enhancement of photoconductivity (150%), an increase in response (400%) and an overall improvement of their dynamic behaviour were observed.
منابع مشابه
Electrostatic Assembly of Platinum Nanoparticles along Electrospun Polymeric Nanofibers for High Performance Electrochemical Sensors
A novel polyacrylonitrile (PAN) nanofibrous membrane conjugated with platinum nanoparticles (PtNPs) was fabricated by electrospinning and electrostatic assembly techniques. In this procedure, PAN was electrospun with 3-aminopropyltriethoxysilane (APS) together as precursor materials. First, amine groups were introduced onto PAN nanofibers, and then the as-prepared negative-charged platinum nano...
متن کاملCatalytically Graphitized Electrospun Carbon Nanofibers Adorned with Nickel Nanoparticles for Catalysis Applications
Catalytically graphitized electrospun carbon nanofibers adorned uniformly with fine nickel nanoparticles were successfully prepared. The procedure was based on the electrospinning technique and the use of nickel precursor to create both graphitized nanofibers and nickel nanoparticles under a relatively low-temperature heat treatment. The X-ray diffraction and Raman results clearly proved cataly...
متن کاملFluorescent and Colorimetric Electrospun Nanofibers for Heavy-Metal Sensing
The accumulation of heavy metals in the human body and/or in the environment can be highly deleterious for mankind, and currently, considerable efforts have been made to develop reliable and sensitive techniques for their detection. Among the detection methods, chemical sensors appear as a promising technology, with emphasis on systems employing optically active nanofibers. Such nanofibers can ...
متن کاملThe Chemical Deposition Method for the Decoration of Palladium Particles on Carbon Nanofibers with Rapid Conductivity Changes
Palladium (Pd) metal is well-known for hydrogen sensing material due to its high sensitivity and selectivity toward hydrogen, and is able to detect hydrogen at near room temperature. In this work, palladium-doped carbon nanofibers (Pd/CNFs) were successfully produced in a facile manner via electrospinning. Well-organized and uniformly distributed Pd was observed in microscopic images of the res...
متن کاملNanostructuring Platinum Nanoparticles on Ni/Ce0.8Gd0.2O2-δ Anode for Low Temperature Solid Oxide Fuel Cell via Single-step Infiltration: A Case Study
With the aim of promoting the Ni/Ce0.8Gd0.2O2-δ (Ni/GDC20) cermet anodic performance of low temperature solid oxide fuel cell (LT-SOFC) [1], nanostructuring platinum nanoparticles on NiO/GDC composite was done by single-step wet-infiltration of hexachloroplatinic acid hexahydrate (H2PtCl6.6H2O) precursor on NiO/GDC20 composite. The anodic polarization resistance was measured using symmetr...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Nanoscale
دوره 6 15 شماره
صفحات -
تاریخ انتشار 2014